Download Bifunctional Molecular Catalysis by Takao Ikariya, Masakatsu Shibasaki PDF

By Takao Ikariya, Masakatsu Shibasaki

Masakatsu Shibasaki, Motomu Kanai, Shigeki Matsunaga, and Naoya Kumagai: Multimetallic Multifunctional Catalysts for uneven Reactions.- Takao Ikariya: Bifunctional transition metal-based molecular catalysts for uneven syntheses.- Chidambaram Gunanathan and David Milstein: Bond Activation by means of Metal-Ligand Cooperation: layout of ”Green” Catalytic Reactions according to Aromatization-Dearomatization of Pincer Complexes.- Madeleine C. Warner, Charles P. Casey, and Jan-E. Bäckvall: Shvo’s Catalyst in Hydrogen move Reactions.- Noritaka Mizuno, Keigo Kamata, and Kazuya Yamaguchi: Liquid-Phase Selective Oxidation by way of Multimetallic energetic websites of Polyoxometalate-Based Molecular Catalysts.- Pingfan Li and Hisashi Yamamoto: Bifunctional Acid Catalysts for natural Synthesis.- Jun-ichi Ito, Hisao Nishiyama: Bifunctional Phebox Complexes for uneven Catalysis.

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51 References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 1 Introduction A deep understanding of the mechanism of catalytic transformations as well as a great insight into the architecture of molecular catalysts has enabled rational design of sophisticated metal-based molecular catalysts [1–4]. Particularly, much effort has been recently paid to the development of bifunctional molecular catalysts based on the combination of two or more active sites working in concert, to attain highly efficient molecular transformations for organic synthesis.

Nitabaru T, Kumagai N, Shibasaki M (2008) Tetrahedron Lett 49:272 40. Nitabaru T, Nojiri A, Kobayashi M, Kumagai N, Shibasaki M (2009) J Am Chem Soc 131:13860 41. Li C, Ren S-F, Hou J-L, Yi H-P, Zhu S-Z, Jiang XK, Li Z-T (2005) Angew Chem Int Ed 44:5725 42. Nitabaru T, Kumagai N, Shibasaki M (2010) Molecules 15:1280 43. Shibasaki M, Kanai M (2007) Org Biomol Chem 5:2027 44. Kanai M, Kato N, Ichikawa E, Shibasaki M (2005) Synlett 1491 45. Cheon CH, Yamamoto H (2008) J Am Chem Soc 130:9246 46. Marinescu S, Nishimata T, Mohr J, Stoltz BM (2008) Org Lett 10:1039 47.

33 Catalytic Hydrogenation of Carboxylic Acid Derivatives Containing C¼O Double Bonds with Bifunctional Molecular Catalysts . . . . . . . . . . . . . . . . . . . . . . . 1 Heterolytic Cleavage of Molecular Hydrogen with Bifunctional Catalysts . . . . . . 2 Hydrogenation of Imides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Hydrogenation of N-Acylcarbamates and N-Acylsulfonamides .

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