Download Batchwise Dyeing of Woven Cellulosic Fabrics by G. W. Badaras, G. W. Madaras, J. Shore PDF

By G. W. Badaras, G. W. Madaras, J. Shore

This booklet is one other within the sequence on color and colour know-how initiated via the Textbooks Committee of the Society of Dyers and Colourists below the aegis of the Dyers' corporation courses belief administration Committee, which administers the belief fund generously supplied by way of the Worshipful corporation of Dyers. it's been written to interchange the former paintings during this sequence entitled The dyeing of cellulosic fibres, that is now out of print. Assembled as a rule approximately fifteen years in the past less than the editorship of Cliff Preston and finally released in 1986, that multi-author ebook had develop into slightly superseded. instead of arrange a proper moment version, Textbooks Committee determined to move for a converted process. A smaller group of authors used to be appointed on the way to finishing the replace extra fast and attaining a extra coherent presentation of the contents.

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For many purposes this is adequate. Nevertheless, a more detailed picture of the fine structure of cellulose can be obtained by what has been termed chemical microstructural analysis (CMA) by workers at the Southern Regional Research Center of the US Department of Agriculture, who have used it extensively [34]. The method was pioneered at the Shirley Institute [51,107,108] and entailed the methylation of cotton by a succession of treatments with diazomethane in water-saturated ether. Total hydrolysis of the products yielded the seven possible mono-, di- and trimethylglucoses and their proportions were measured by gas–liquid chromatography.

Some depolymerisation is desirable in most commercial products, but its extent needs to be carefully controlled. Although interest in cellulose derivatives lies mainly in their industrial Contents Home 42 CELLULOSE: STRUCTURE, PROPERTIES AND BEHAVIOUR IN THE DYEING PROCESS applications, it must not be forgotten that they have played an important role in the establishment of the chemical structure of cellulose [30,82]. Direct acid hydrolysis is unsatisfactory for structural studies, partly because the glucose produced is often subject to further change under the conditions employed.

3) The mechanical properties of cellulosic fibres vary with their moisture content. (4) The comfort of clothing made from cellulosic fibres is closely associated with moisture absorbency. 12) might lead one to expect that cellulose would be soluble in water, as glucose is. In fact, of course, it is not. It is Contents Home AFFINITY FOR WATER AND ORGANIC LIQUIDS 49 generally accepted that water cannot penetrate cellulose crystallites [173]. The intermolecular hydrogen bonds holding the crystallites together are no stronger than those between water and cellulosic hydroxy groups.

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