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By Edited by Pietro VINCENZINI World Academy of Ceramics and National Research Council, Italy Co-edited by Michele DONDI CNR-ISTEC, Italy

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Extra info for 12th INTERNATIONAL CERAMICS CONGRESS PART G Proceedings of the 12 th International Ceramics Congress, part of CIMTEC 2010- 12 th International Ceramics Congress and 5th Forum on New Materials Montecatini Terme, Italy, June 6-11, 2010

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Results Reaction Scheme and sample preparation. The principles of hybrid lamellar silica synthesis are depicted on Fig. 1. First, the ammonium surfactant bearing two long alkyl chains is stirred in an acidified water solution. The mixture is allowed to equilibrate in order to reach a complete organization of the template molecules into an ordered lamellar mesophase. Then the precursor of silica (tetraethylorthosilicate) is added and after 24h of reaction, the SiO2 solid which has the symmetry of the surfactant mesophase is washed until a 5-6 pH is reached.

Kaolin are complex mixtures of more or less ordered kaolinite, a mica group mineral and quartz, and minor minerals can be present. Mullite crystallization is the most frequent phenomenon involved in the structural transformation of clay minerals. The quantity and development of this phase influence the sintering mechanisms, but mullite formation depends on the raw material type and is modified by the firing process [1 2 3 4]. In this paper, we present mullite crystallization from a kaolin raw material containing kaolinite as the major mineral and muscovite and quartz as minor minerals.

Hoff, C. Hall, and B. McKay: J. Phys. D: Appl. Phys. Vol. 41 (2008), p 055402 [14] M. A. Wilson, M. A. Carter, C. Hall, W. D. Hoff, C. Ince, S. Savage, B. McKay, and I. Betts: Proc. R. Soc. A Vol. 465 (2009), p. 2407 [15] S. Lee, Y. J. Kim and H. S. Moon: J. Amer. Ceram. Soc. Vol. 82 (1999), p. be, Keywords: Hybrid, lamellar, silica, templating, mesoporous, silane. Abstract. This paper is focused on the preparation and characterization of different lamellar silica prepared by liquid crystal templating and silanisation.

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